(E)-N′-(2-Chloro-5-nitrobenzylidene)-4-methoxybenzohydrazide

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(E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide

The title compound, C(14)H(12)ClN(3)O(2), displays an E conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 41.3 (5)°. The mol-ecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal, N-H⋯O and weak N-H⋯Cl hydrogen bonds link the mol-ecules into a three-dimensional architecture. In addition, there are weak C-H⋯π stac...

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(E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide

In the title hydrazide Schiff base compound, C(14)H(12)ClN(3)O(2), the conformation around the C=N double bond is E. The dihedral angle between the benzene rings is 41.57 (14) Å. An intra-molecular O-H⋯N hydrogen bond makes an S(6) ring motif. In the crystal, mol-ecules are linked by N-H⋯O (bifurcated acceptor) and N-H⋯N hydrogen bonds, forming chains along the a axis. The inter-esting feature ...

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(E)-4-Chloro-N′-(5-hydr­oxy-2-nitro­benzyl­idene)benzohydrazide

The title compound, C(14)H(10)ClN(3)O(4), was synthesized by the reaction of 5-hydr-oxy-2-nitro-benzaldehyde with an equimolar quantity of 4-chloro-benzohydrazide in methanol. The mol-ecule displays an E configuration about the C=N bond. The dihedral angle between the two benzene rings is 3.9 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O and O-H⋯O hydrogen ...

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(E)-N′-(2-Chloro-5-nitro­benzyl­idene)-4-methoxy­benzohydrazide

In the title compound, C(15)H(12)ClN(3)O(4), the benzohydrazide group is not planar and the mol-ecule exists in a trans configuration with respect to the methyl-idene unit. The dihedral angle between the two substituted benzene rings is 0.4 (3)°. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming chains parallel to the c axis.

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N′-(5-Chloro-2-hydroxy­benzyl­idene)-4-hydroxy­benzohydrazide

The title Schiff base compound, C(14)H(11)ClN(2)O(3), was prepared by the reaction of 5-chloro-salicylaldehyde and 4-hydroxy-benzohydrazide. The mol-ecule exists in a trans configuration with respect to the methyl-idene group. The dihedral angle between the two benzene rings is 40.1 (2)°. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular conformation. In the crystal struc...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808034107